کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
4767353 | 1424132 | 2017 | 34 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Core-shell structured ZnS-C nanoparticles with enhanced electrochemical properties for high-performance lithium-ion battery anodes
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Core-shell structured ZnS-C nanoparticles are successfully synthesized by a chitosan-assisted hydrothermal method followed by a chemical vapor deposition process using C2H2. The ZnS nanoparticles (c.a. 100-150 nm in size) are uniformly coated by a thin carbon shell with a thickness of about 10 nm, forming well-dispersed nano-powders. When applied as anode in lithium cells, the synthesized nano-ZnS-C composite exhibits a specific capacity of 565 mAh gâ1 at 0.1 A gâ1 and 363 mAh gâ1 at 5 A gâ1 current density. After 600 cycles at a current density of 0.5 A gâ1, the constructed electrode shows over 87% capacity retention, indicating excellent electrochemical performance. The outstanding properties of the obtained nano-ZnS-C can be attributed to the well-defined core-shell nanostructure, in which the nano-sized ZnS core provides short lithium ion diffusion pathways, while the carbon shell allows for a fast electron conduction, and at the same time accommodates the volume changes caused by the lithiation/delithiation of ZnS.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 225, 20 January 2017, Pages 129-136
Journal: Electrochimica Acta - Volume 225, 20 January 2017, Pages 129-136
نویسندگان
Xuefei Du, Hailei Zhao, Zijia Zhang, Yao Lu, Chunhui Gao, Zhaolin Li, Yongqiang Teng, Lina Zhao, Konrad Åwierczek,