کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
4767612 | 1424131 | 2017 | 11 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Redox properties of polyelectrolyte multilayer modified electrodes: a significant effect of the interactions between the polyelectrolyte layers in the films
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موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The layer-by-layer (LbL) sequential adsorption of oppositely charged polyelectrolytes leads to the formation of multilayered films (Polyelectrolyte Multilayer, PEM). Such systems may find application as ultrathin membranes with controlled properties. In this paper we examine different polyelectrolyte multilayers formed from poly-L-lysine (PLL), polyethyleneimine (PEI), poly(sodium 4-styrenesulfonate) (PSS) and alginate (ALG) polyelectrolytes. Film thicknesses for the PLL/PSS, PLL/ALG and PEI/PSS combinations showed similar values of up to 14Â nm on mica and ca. 22Â nm on platinum surfaces. The PEI/ALG combination formed thicker films with thicknesses of up to 90Â nm on mica and ca. 140Â nm on platinum surfaces. For the prepared films, the electroactive behavior towards [Fe(CN)6]3â/4â and [Ru(NH3)6]3+/2 ions was monitored. We found that the oxidation/reduction current of [Fe(CN)6]3â/4â ions showed three different modes of behavior which can be described as non-permeability, permeability and accumulation of ions. For [Ru(NH3)6]3+/2+ such a relation was not observed and all of the films remained permeable. The permeability of the thin PEMs seems to depend more strongly on the film composition than the film thickness. The best candidate for encapsulation purposes is proposed.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 226, 1 February 2017, Pages 121-131
Journal: Electrochimica Acta - Volume 226, 1 February 2017, Pages 121-131
نویسندگان
Marcin Strawski, Ludomira H. Granicka, Marek Szklarczyk,