کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
4767730 | 1424143 | 2016 | 26 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Electrochemical deposition and dissolution of Fe species for N-doped carbon to understand the degradation mechanism of Pt-free oxygen reduction catalysts
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موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
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چکیده انگلیسی
The enhancement in oxygen reduction reaction (ORR) activity is achieved by the introduction of Fe species via the Fe electrochemical deposition-dissolution treatment into a metal-free nitrogen-doped carbon (P-PI) catalyst, which is prepared by the pyrolysis of polyimide fine particles. The thus-obtained Fe-containing P-PI catalyst suffers activity decay during the durability test, evidenced by the negative shift of half-wave potential, the decrease in limiting current density, the number of electrons transferred, and the ratio of the rate constant for 4-electron ORR to that for 2-electron process, and the increase in H2O2 production percentage. The decayed ORR activity can be recovered by another Fe electrochemical deposition-dissolution treatment, demonstrating the predominant role of Fe leaching in activity degradation as well as the effectiveness of the electrochemical treatment in activity restoration.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 214, 1 October 2016, Pages 307-312
Journal: Electrochimica Acta - Volume 214, 1 October 2016, Pages 307-312
نویسندگان
Jiajia Wu, Yuta Nabae, Azhagumuthu Muthukrishnan, Takeo Ohsaka,