کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
4769553 1426203 2017 29 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Thermodynamic behavior of {ethanol + butylpyridinium tetrafluoroborate} binary solution in the critical region
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Thermodynamic behavior of {ethanol + butylpyridinium tetrafluoroborate} binary solution in the critical region
چکیده انگلیسی
The liquid-liquid coexistence curve, heat capacity, and turbidity of binary solution {ethanol + butylpyridinium tetrafluoroborate]} have been precisely measured. The critical exponents and critical amplitudes corresponding to the heat capacity, width of coexistence curve, osmotic compressibility, and correlation length were obtained. The critical exponents and critical amplitude ratios showed well agreements with the theoretical values of the 3D-Ising universality class. The asymmetric behavior of the coexistence curve diameter was found to be well described by the complete scaling theory with the consideration of the heat capacity related term.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: The Journal of Chemical Thermodynamics - Volume 110, July 2017, Pages 211-217
نویسندگان
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