کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
47960 46486 2009 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Visible light photocatalytic activity of TiO2/D-PVA for MO degradation
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
پیش نمایش صفحه اول مقاله
Visible light photocatalytic activity of TiO2/D-PVA for MO degradation
چکیده انگلیسی

A novel visible light (VL) active photocatalyst (TiO2/D-PVA) was prepared in one portion of polyvinyl alcohol (PVA) and Ti(OH)4 by means of hydrothermal method, and the relationship between the prepared conditions and VL photocatalytic activity was investigated. The synthesized photocatalyst was characterized by XRD, UV–vis, XPS, FTIR and EPR. The results show that PVA was dehydrated to produce conjugated unsaturated D-PVA. The VL photocatalytic activity was attributed to the interaction between D-PVA and TiO2. The TiO2/D-PVA, synthesized with the 1:10 feed ratio of PVA to TiO2 at 180 °C, exhibited a significant VL activity for the Methyl orange (MO) degradation. The degradation rate fit the characteristic of apparent first-order kinetics. The mechanism of MO degradation was also proposed.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Applied Catalysis B: Environmental - Volume 90, Issues 1–2, 25 July 2009, Pages 249–254
نویسندگان
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