کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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48287 | 46499 | 2008 | 11 صفحه PDF | دانلود رایگان |
In this work we describe the application of a new non-soluble and non-porous complex with copper ion based on ethylene glycol diglycidyl ether (EGDE), methacrylic acid (MAA) and 2-methylimidazole (2MI) in the decolorization of an azo dye Methyl Orange (MO) as a model pollutant at room temperature.The complex with copper ion was studied by ESR and SEM and was tested as a heterogeneous catalyst for H2O2 activation. A possible mechanism of interaction involves the production of hydroxyl radicals (confirmed by ESR), dioxygen and water.The Cu(II)-polyampholyte/H2O2 system acted efficiently in the color removal of MO. The adsorption and oxidative degradation of the azo-based dye followed pseudo-first-order kinetic profiles, and the rate constant for degradation had a second-order dependence on copper ion content in the mixture.A removal of MO higher than 90% was achieved in 20 min at pH 7.0, combining 0.8 mM of complexed copper ions in the mixture with 24 mM hydrogen peroxide.The dye adsorbed on the polyampholyte following a L4-type isotherm with 4.9 μmol g−1 maximum loading capacity and 3.1 μM dissociation constant for the first monolayer.
Journal: Applied Catalysis B: Environmental - Volume 82, Issues 3–4, 8 August 2008, Pages 273–283