کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
48579 | 46513 | 2007 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
On the promoting effect by quaternary ammonium salts in the multiphase hydrodechlorination with hydrogen gas on Raney nickel catalyst
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
کاتالیزور
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: On the promoting effect by quaternary ammonium salts in the multiphase hydrodechlorination with hydrogen gas on Raney nickel catalyst On the promoting effect by quaternary ammonium salts in the multiphase hydrodechlorination with hydrogen gas on Raney nickel catalyst](/preview/png/48579.png)
چکیده انگلیسی
Hydrodechlorination of 1,3,5-trichlorobenzene with hydrogen gas on Raney nickel catalyst in the biphasic system composed of isooctane, aqueous KOH, and a quaternary ammonium compound as a promoter at 70 °C and atmospheric pressure was studied. The promoter increased the rate of reaction above two orders of magnitude. Several quaternary chloride salts were studied, such as Aliquat 336, trioctylmethylammonium, tridodecylmethylammonium, cetyltrimethylammonium, tetrabutylammonium and tetraethylammonium. The relationship of the reaction rate with adsorption, micelle formation, and the structural properties of the promoter are discussed.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Applied Catalysis B: Environmental - Volume 75, Issues 1–2, 29 August 2007, Pages 124–128
Journal: Applied Catalysis B: Environmental - Volume 75, Issues 1–2, 29 August 2007, Pages 124–128
نویسندگان
Sergei Zinovyev, Pietro Tundo,