کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
4863 251 2007 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Enzymatic polymerization of o-phenylendiamine with cytochrome c activated by a calixarene derivative in organic media
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی بیو مهندسی (مهندسی زیستی)
پیش نمایش صفحه اول مقاله
Enzymatic polymerization of o-phenylendiamine with cytochrome c activated by a calixarene derivative in organic media
چکیده انگلیسی

Cytochrome c can be dissolved in organic media through complexation with a macrocyclic compound calix[6]arene carboxylic acid derivative. Enzymatic oxidation of o-phenylenediamine with the cytochrome c complex as a catalyst was demonstrated in organic media. The cytochrome c complex displays peroxidase activity in the presence of hydrogen peroxide. Enzymatic polymerization of o-phenylenediamine was examined under optimal conditions. A polymer product was effectively obtained in hexane or chloroform; however, a monomeric compound was also in the product. In this paper, a novel solubilization method utilizing enzymes and their uses as catalysts in organic media are described.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Biochemical Engineering Journal - Volume 35, Issue 1, 1 July 2007, Pages 66–70
نویسندگان
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