کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
4907315 | 1426202 | 2017 | 11 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Thermophysical properties of 1,2,4-trimethylbenzene in admixtures with 1-butanol or 2-butanol at high pressures
ترجمه فارسی عنوان
خواص ترموفیزیکی 1،2،4 تریمتی بنزن در مواد افزودنی با 1-بوتانول یا 2-بوتانول در فشار بالا
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
چکیده انگلیسی
The systems of 1-butanol or 2-butanol + 1,2,4-trimethylbenzene were characterized measuring densities and isobaric heat capacities at high pressures. Densities of 2-butanol and 1,2,4-trimethylbenzene and the binary systems 1-butanol or 2-butanol + 1,2,4-trimethylbenzene were measured at the ranges p = (0.1-140) MPa and T = (273.15-333.15) K. For these measurements, a high-pressure vibrating tube densimeter was used and data were successfully correlated with the empirical Tammann-Tait equation. In order to complete the characterization, isobaric heat capacities were measured over the range of (0.1-25) MPa at two different temperatures (293.15 and 313.15) K for the same pure compounds and binary mixtures. These measurements were performed in a high-pressure automated flow calorimeter. Excess molar heat capacities were evaluated for the mixtures and a positive deviation from the ideality was obtained for both systems.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: The Journal of Chemical Thermodynamics - Volume 111, August 2017, Pages 41-51
Journal: The Journal of Chemical Thermodynamics - Volume 111, August 2017, Pages 41-51
نویسندگان
Geraldine A. TorÃn-Ollarves, M. Carmen MartÃn, José J. Segovia,