کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
4907467 1426206 2017 10 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Cibulka correlation for ternary excess/deviation properties of {[C2mim][EtSO4] (x1) + acetic or propionic acid (x2) + acetonitrile (x3)} systems at different temperatures
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Cibulka correlation for ternary excess/deviation properties of {[C2mim][EtSO4] (x1) + acetic or propionic acid (x2) + acetonitrile (x3)} systems at different temperatures
چکیده انگلیسی
In this perspective, the main intention is to reveal the possible intra and inter molecular interactions between ternary ionic liquid systems. The excess molar volume (V123E), isentropic compressibility (ks) and deviation in isentropic compressibility (Δks123) were determined for two ternary liquid mixtures of {[C2mim][EtSO4] (x1) + acetic or propionic acid (x2) + acetonitrile (x3)} at different temperatures (293.15, 298.15, 303.15, 308.15 and 313.15) K and at p = 1 × 105 Pa with the aid of the experimental density (ρ) and speed of sound (u) measurements. The calculated ternary excess volume and deviation in isentropic compressibility results were correlated by using the Cibulka equation with the aid of Redlich-Kister parameters obtained from literature corresponding binary systems. Furthermore, the measured thermodynamic properties are discussed in terms of molecular interactions between component molecules in liquid mixtures.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: The Journal of Chemical Thermodynamics - Volume 107, April 2017, Pages 153-162
نویسندگان
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