کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
4907969 1426584 2017 27 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Nitrogen-doped microporous carbon from polyaspartic acid bonding separator for high performance lithium-sulfur batteries
ترجمه فارسی عنوان
کربن مایع منفرد نیتروژن از جدا کننده پیوند اسید پلیاسترکتیک برای باتری های لیتیوم-سولفور با کارایی بالا
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
چکیده انگلیسی
Lithium-sulfur (Li-S) batteries are regarded as one of the great potential members for the next-generation rechargeable batteries due to their outstanding theoretical energy density (2600 Wh kg− 1), low cost and environment friendliness. However, the further developments of Li-S batteries have been obstructed by the low electronic conductivity of active material and the diffusion of polysulfides. In this paper, we found a cheap raw material to prepare a nitrogen doped porous carbon (NPC) by a simple method. Then, NPC was used to modify the pristine separator to promote the overall performance of Li-S batteries. With the NPC modified separator, a high initial discharge capacity of 1382 mAh g− 1 at 0.2 C and a low fading rate of 0.078% per cycle within 500 cycles at 0.5 C can be delivered by the pure sulfur cathode (1 C = 1675 mAh g− 1), which attribute to the high-content nitrogen doped level and large specific surface area of NPC. This shows a great potential for the scale-up applications of Li-S batteries.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Electroanalytical Chemistry - Volume 791, 15 April 2017, Pages 167-174
نویسندگان
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