کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
4908696 | 1362583 | 2017 | 10 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Facile synthesis, characterization, and adsorption properties of Cd (II) from aqueous solution using β-cyclodextrin polymer impregnated in functionalized chitosan beads as a novel adsorbent
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
This study explores the adsorption capacity of carboxymethyl-β-cyclodextrin (CMβ-CD) functionalized chitosan (CS) impregnated with water-insoluble epichlorohydrin cross-linked β-cyclodextrin polymer (β-CDP) to yield CS-β-CDP-CMβ-CD composite beads for the removal of toxic Cd (II) ions from aqueous solutions. Characterization of the adsorbent was performed with XPS, FTIR, NMR, BET and SEM. The synergistic effect was expected and found at removing Cd (II) with a sorption capacity exceeding 378 mg gâ1 (approximately 3.37 mmol gâ1), which is higher than any other existing technology. The removal of Cd (II) was found maximum at pH 6.5. The rate reduction can be expressed by pseudo-second-order reaction kinetics. Thermodynamic parameters such as the enthalpy (ÎH0), entropy (ÎS0), and free energy change (ÎG0) suggest the endothermic adsorption of Cd (II) in solution. The activation energy was calculated to be 65.62 kJ molâ1 indicating a chemisorption process. The regeneration and reusability of the adsorbent were found suitable for in situ application of this technology for Cd remediation. The Langmuir isotherm model, which is effective for analyzing equilibrium data, indicated both monolayer adsorption and chemisorption. The intraparticle diffusion model indicated both film diffusion and intraparticle diffusion as the rate limiting steps. Thus, the synthesized CS-β-CDP-CMβ-CD beads showed good adsorption selectivity for Cd (II) having excellent regeneration and reusability.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Environmental Chemical Engineering - Volume 5, Issue 4, August 2017, Pages 3395-3404
Journal: Journal of Environmental Chemical Engineering - Volume 5, Issue 4, August 2017, Pages 3395-3404
نویسندگان
Md. Tajuddin Sikder, Md. Jakariya, Md. Mostafizur Rahman, Sayaka Fujita, Takeshi Saito, Masaaki Kurasaki,