کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
4988566 1455954 2018 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Polyamide-crosslinked graphene oxide membrane for forward osmosis
ترجمه فارسی عنوان
غشاء اکسید گرافین پلی اتیلن با همدیگر برای اسمز معکوس
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی تصفیه و جداسازی
چکیده انگلیسی
A novel polyamide-graphene oxide (PA-GO) membrane was synthesized on a polyethersulfone support by first intra-crosslinking GO aggregates via m-xylylenediamine (MXDA) and then inter-crosslinking GO aggregates via trimethyle chloride (TMC). This method allows for the use of hydrophilic, more porous supports in forward osmosis (FO) membranes, thereby lending much flexibility to membrane synthesis and also potentially reducing internal concentration polarization in FO. The elemental composition, morphology, and hydrophilicity of the synthesized PA-GO membrane were characterized to confirm intra- and inter-crosslinking reactions and understand membrane properties. It was found that the mixing temperature of MXDA and GO should be controlled below 20 ℃ to avoid the formation of large GO aggregates and hence reduce membrane heterogeneity and defects. The performance of the PA-GO membrane was compared with that of a commercial FO membrane using trisodium citrate (TSC), Na2SO4, and MgCl2, respectively, as draw solutes. Under the same osmotic pressure, the water flux of the PA-GO membrane was the highest with TSC as draw solute, moderate with Na2SO4, and almost zero with MgCl2, while the ranking of solute fluxes followed a reverse order, revealing that an effective solute barrier plays an important role in making FO membranes with high water flux and low solute flux.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Membrane Science - Volume 545, 1 January 2018, Pages 11-18
نویسندگان
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