کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
4997609 | 1459914 | 2017 | 11 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Effect of Ethylenediamine-N,Nâ²-disuccinic acid (EDDS) on the speciation and bioavailability of Fe2+ in the presence of sulfide in anaerobic digestion
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
تکنولوژی و شیمی فرآیندی
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چکیده انگلیسی
The effects of a biodegradable chelating agent, Ethylenediamine-N,Nâ²-disuccinic acid (EDDS), on the speciation and bioavailability of iron (Fe2+) in anaerobic digestion were examined. Fe2+ supplementation at 10Â mg/L increased methane yield, but the presence of 8Â mg/L sulfide led to the precipitation of Fe2+ as FeS which limited its bioavailability. The results confirmed that the EDDS could replace common chelating agents with low biodegradability (EDTA and NTA), and improve the bioavailability of Fe2+ by forming an Fe-EDDS complex, thereby protecting Fe2+ from sulfide precipitation. Experimental findings from sequential extraction using the Community Bureau of Reference (BCR) method, and quantification of free EDDS and Fe-EDDS complex using UHPLC, confirmed that 29.82% of Fe2+ was present in bioavailable forms, i.e. soluble and exchangeable, when EDDS was added at 1:1 molar ratio to Fe2+. As a result, the methane production rate increased by 11.17%, and the methane yield increased by 13.25%.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Bioresource Technology - Volume 229, April 2017, Pages 169-179
Journal: Bioresource Technology - Volume 229, April 2017, Pages 169-179
نویسندگان
Pham Minh Thanh, Balachandran Ketheesan, Zhou Yan, David Stuckey,