کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
50480 46796 2015 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Graphene oxide as a facile solid acid catalyst for the production of bioadditives from glycerol esterification
ترجمه فارسی عنوان
اکسید گرافن به عنوان یک کاتالیزور اسیدی جامد اسیدی برای تولید مواد زیستی از استرینگ سازی گلیسرول
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
چکیده انگلیسی


• GO is a highly active, selective and reusable catalyst for glycerol esterification.
• A 90.2% combined selectivity of glyceryl diacetate and triacetate was achieved.
• GO can reuse four consecutive runs without obvious deactivation.
• SO3H groups of GO were identified as the active species for glycerol esterification.

Graphene oxide (GO) has proved to be a highly active and reusable solid acid catalyst for glycerol esterification with acetic acid in the synthesis of bioadditives diacylglycerol (DAG) and triacylglycerol (TAG). The effects of reaction temperature, molar ratio of acetic acid to glycerol, catalyst amount and reaction time were investigated. A 90.2% combined selectivity of DAG and TAG with complete glycerol conversion was achieved at 120 °C for 6 h over GO. Final characterization shows that the active site of GO is the remaining SO3H group.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Catalysis Communications - Volume 62, 5 March 2015, Pages 48–51
نویسندگان
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