کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5117140 1485227 2017 10 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Phenolic sensor development based on chromium oxide-decorated carbon nanotubes for environmental safety
ترجمه فارسی عنوان
توسعه سنسورهای فنولوژیک بر اساس نانولوله های کربن تزئینی کروم برای ایمنی زیست محیطی
موضوعات مرتبط
مهندسی و علوم پایه مهندسی انرژی انرژی های تجدید پذیر، توسعه پایدار و محیط زیست
چکیده انگلیسی


- Cr2O3- CNT nanocomposite was prepared by solution method.
- A fast response towards 4-methoxyphenol was developed.
- Sensor sensitivity was 1.4768 μA cm−2 μM−1.
- Sensor detection limit was 0.06428 ± 0.0002 nM.
- Environmental safety.

A nanocomposite (NC) composed of chromium(III)oxide nanomaterials decorated carbon nanotubes (Cr2O3-CNT NC) was prepared via a simple solution method with reducing agents in an alkaline medium. The Cr2O3-CNT NC was characterized using ultraviolet-visible (UV/Vs.) spectroscopy, Fourier-transform infrared (FTIR) spectroscopy, energy-dispersive X-ray spectroscopy (XEDS), X-ray powder diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and field-emission scanning electron microscopy (FESEM). The Cr2O3-CNT composite was deposited on a flat glassy carbon electrode (GCE) with conducting nafion (5%) binders to produce a sensor that exhibited fast response and high selectivity toward 4-methoxyphenol (4MP) in phosphate buffer phase at pH 7. Furthermore, the sensor performance parameters, including the sensitivity, lower detection range, reliability, and reproducibility, ease of integration, long-term stability, and selectivity were investigated in detail. The calibration plot was found to be linear in the concentration range of 0.01 nM-0.1 μM. The sensitivity and detection limit were calculated as 1.4768 μA cm−2 μM−1 and 0.06428 ± 0.0002 nM (at a signal-to-noise ratio of 3), respectively. Thus, it was concluded that the proposed selective and efficient sensor represents a promising approach to effectively detect toxic phenolic compounds in the environment with acceptable and reliable results.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Environmental Management - Volume 188, 1 March 2017, Pages 228-237
نویسندگان
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