کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5131141 | 1490874 | 2017 | 8 صفحه PDF | دانلود رایگان |
- This paper provides the first hydrothermal synthesis of platinum nanoclusters.
- The prepared polyethylenimine-protected platinum nanoclusters possess high quantum yield of 28%.
- A new method to detect trace amount of metronidazole in urine is proposed.
A novel one-step hydrothermal synthesis of highly fluorescent platinum nanoclusters protected by polyethylenimine (Pt-NCs@PEI) is described. The products are characterized well by UV-vis absorption, fluorescence spectra, X-ray photoelectron spectroscopy (XPS) and transmission electron microscopy (TEM) imaging. The Pt-NCs@PEI possess high quantum yield at 28%, which is the relatively high one among the reported Pt-NCs; especially, the synthesis is in one-step and the reaction time is much shorter (<1 h) than the related methods. In addition, the Pt-NCs@PEI have large Stocks-shift (â¼150 nm), high tolerability to the extreme pH and high ionic strengths, and excellent photo-stability under UV-vis irradiation, lay the foundation for the practical bio-applications. Finally, the obtained Pt-NCs@PEI are used to determine trace amount of metronidazole (MTZ) in buffer solution in showing a linear response over a concentration range of 0.25-300 μM and a low detection limit of 0.1 μM. Furthermore, the related investigation on response mechanism will be helpful to design and synthesize new metal nanoclusters as fluorescent probe to detect the trace amount of harmful medicine residuum as nitroimidazoles in human body.
160
Journal: Analytica Chimica Acta - Volume 958, 15 March 2017, Pages 51-58