کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5134577 | 1492953 | 2017 | 9 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: New insights into microwave pyrolysis of biomass: Preparation of carbon-based products from pecan nutshells and their application in wastewater treatment New insights into microwave pyrolysis of biomass: Preparation of carbon-based products from pecan nutshells and their application in wastewater treatment](/preview/png/5134577.png)
- Microwave pyrolysis of nutshell to produce carbon-based products for lead removal.
- NMR, dielectric characterization, SEM/EDX, SBET, XRD to monitor intermediate products.
- Microwave leads to simultaneous (hemi)cellulosic and lignin degradation.
- Ion-exchange by calcium ions on the material surface promotes the lead removal.
- Calcium compound development directly related to microwave interaction with biomass.
Microwave pyrolysis of pecan nutshell (Carya illinoinensis) biomass was used to produce carbon-based solid products with potential application in contaminated water treatment.A range of analytical techniques were applied to characterize the intermediate products of microwave pyrolysis in order to monitor the physico-chemical effects of the interacting energy on the biomass.The performance of the carbon-based products was tested through evaluation of lead ion removal capacity from solution. Further analyses demonstrated that ion-exchange by calcium ions on the material surface was the main mechanism involved in lead removal. Calcium compound development was directly correlated to the interaction of the electromagnetic waves with the biomass.Through monitoring the physico-chemical effects of biomass-microwave interactions during microwave pyrolysis, we have shown for the first time that the intermediate products differ from those of conventional pyrolysis. We hypothesize that selective heating leads to the (hemi)cellulosic and lignin degradation processes occurring simultaneously, whereas they are largely sequential in conventional pyrolysis.This work provides optimization parameters essential for the large scale design of microwave processes for this application as well as an understanding of how the operating parameters impact on functionality of the resulting carbon-based materials.
179
Journal: Journal of Analytical and Applied Pyrolysis - Volume 124, March 2017, Pages 113-121