کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5141907 | 1495967 | 2017 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Raman spectroscopy of l,l-diphenylalanine crystal under high pressure
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Raman spectroscopy of l,l-diphenylalanine crystal under high pressure Raman spectroscopy of l,l-diphenylalanine crystal under high pressure](/preview/png/5141907.png)
چکیده انگلیسی
The l,l-diphenylalanine can self-assemble into long and stiff nanotubes with remarkable mechanical and chemical stability. In this work, Raman spectroscopy was used to investigate the vibrational properties of l,l-diphenylalanine single crystal under high-pressure conditions up to 7.4Â GPa. The results show great modifications in the low-wavenumber bands accompanied by some changes in the internal mode vibrations between 3.9 and 4.6Â GPa, indicating the occurrence of a structural phase transition. Since the coupling between water molecules and the nanochannels of the l,l-diphenylalanine crystal is extremely sensitive to the tubular arrangement, the vibrational changes observed in the spectral region of internal modes can be interpreted as conformational modifications in the dipeptide backbone. On decompression, we found that the phase transition is reversible since the ambient spectrum is recovered when the pressure is completely released.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Vibrational Spectroscopy - Volume 92, September 2017, Pages 173-181
Journal: Vibrational Spectroscopy - Volume 92, September 2017, Pages 173-181
نویسندگان
J.G. da Silva Filho, J. Mendes Filho, F.E.A. Melo, J.A. Jr., P.T.C. Freire,