کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5145198 | 1497339 | 2017 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Highly active Pt decorated Pd/C nanocatalysts for oxygen reduction reaction
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
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چکیده انگلیسی
This article describes findings of the correlation between the atomic scale surface structure and the electrocatalytic performance of nanoengineered Pt-Pd/C catalysts for oxygen reduction reaction (ORR), aiming at providing a new fundamental insight into the role of the detailed atomic decorated structure of the catalysts in fuel cell reactions. Carbon-supported Pt decorated Pd nanoparticles (donated as Pt-Pd/C), with Pt coverage close to a monolayer, were prepared from a simple galvanic replacement reaction between Pd/C particles and PtCl42â at room temperature. The decorated architecture was confirmed by extensive microstructural characterization techniques, including TEM, XRD, XPS, HAADF-STEM, ICP and HS-LEIS. The catalysts were also examined for their intrinsic kinetic activities towards oxygen reduction reaction. The results have shown that the Pt-Pd/C catalysts are highly active towards molecular oxygen electrocatalytic reduction. These findings have profound implications to the design and nanoengineering of decorated surfaces of catalysts for oxygen reduction reaction.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: International Journal of Hydrogen Energy - Volume 42, Issue 38, 21 September 2017, Pages 24090-24098
Journal: International Journal of Hydrogen Energy - Volume 42, Issue 38, 21 September 2017, Pages 24090-24098
نویسندگان
Mengyin Liao, Weiping Li, Xiping Xi, Chenglong Luo, Yinxuan Fu, Shuanglin Gui, Zhaohuan Mai, Heng Yan, Cheng Jiang,