کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5146411 | 1497351 | 2017 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Remarkable catalytic activity of electrochemically dealloyed platinum-tellurium nanoparticles towards formic acid electro-oxidation
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Aiming to improve the activity of Pt-based catalysts for formic acid electro-oxidation, dealloyed PtxTey/C catalysts were prepared via electrochemical leaching process. The dealloyed-Pt3Te/C catalyst presented superior activity and stability for formic acid electro-oxidation. The mass activities of dealloyed-Pt3Te/C at 0.25Â V and 0.4Â V vs. SCE were about 10.6 and 16.5 times as high as that of commercial Pt/C, respectively. It is found that the FAEO on D-Pt3Te/C is mainly through dehydrogenation pathway. The weak CO adsorption, increased electrochemical specific area and ensemble effect are suggested as reasons for the remarkable enhancement.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: International Journal of Hydrogen Energy - Volume 42, Issue 26, 29 June 2017, Pages 16489-16494
Journal: International Journal of Hydrogen Energy - Volume 42, Issue 26, 29 June 2017, Pages 16489-16494
نویسندگان
Feilong Zhou, Jinwei Chen, Yichun Wang, Jie Zhang, Xiaoyang Wei, Rui Luo, Gang Wang, Ruilin Wang,