کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5146415 | 1497351 | 2017 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Co(OH)2 nanoparticles deposited on reduced graphene oxide nanoflake as a suitable electrode material for supercapacitor and oxygen evolution reaction in alkaline media
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله

چکیده انگلیسی
In this work, cobalt hydroxide nanoparticles are simply synthesized (size is about 50 nm) and deposited on the reduced graphene oxide nanoflake by the hydrothermal method. Then, the ability of glassy carbon electrode modified with this low-cost nanocomposite is examined as a supercapacitor and oxygen evolution electrocatalysts in 2.0 mol Lâ1 KOH by a three-electrode system. The modified electrode as a pseudocapacitor with potential windows of 0.35 V, exhibits a powerful specific capacitance (235.20 F gâ1 at 0.1 A gâ1 current density), energy density, stability (about 90% of the initial capacitance value maintain after 2000 cycles at 1.0 A gâ1) and fast charge/discharge ability. Furthermore, the modified electrode displays a good electrocatalytic activity for oxygen evolution reaction with a current density of 10.0 mA cmâ2 at 1.647 V, small Tafel slope of 56.5 mV decâ1, good onset potential of 1.521 V vs. RHE and suitable durability.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: International Journal of Hydrogen Energy - Volume 42, Issue 26, 29 June 2017, Pages 16538-16546
Journal: International Journal of Hydrogen Energy - Volume 42, Issue 26, 29 June 2017, Pages 16538-16546
نویسندگان
Behzad Rezaei, Ahmad Reza Taghipour Jahromi, Ali Asghar Ensafi,