کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5147189 | 1497383 | 2016 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
H2 purification through preferential oxidation of CO over ceria supported bimetallic Au-based catalysts
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
CeO2 supported mono and bimetallic Au catalysts (AuAg, AuCu, AuPd, AuRu), prepared by deposition-precipitation, were tested in the preferential oxidation of CO in the excess of H2 (PROX). Activity data showed that the PROX performances of Au/CeO2 are boosted by addition of Ag and to a minor extent Cu, whereas Ru and Pd have a negative effect. For both AuAg and AuCu systems the deposition order did not affect the catalytic performance whereas 1wt%/1wt% was found as the optimal Au/second metal ratio. On the basis of characterization data (H2-TPR, TG-DTA, DRIFT, Surface Area measurements) it was proposed that the addition of Ag and Cu to Au/CeO2 leads to a higher reactivity of surface ceria oxygen involved in the PROX reaction through a Mars-van Krevelen mechanism. The higher activity of the AuAg/CeO2 system was attributed to the occurrence of a strong mutual interaction between gold and silver that positively affects the PROX performance in terms of yields to CO2 and stability under reaction conditions.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: International Journal of Hydrogen Energy - Volume 41, Issue 42, 9 November 2016, Pages 19390-19398
Journal: International Journal of Hydrogen Energy - Volume 41, Issue 42, 9 November 2016, Pages 19390-19398
نویسندگان
Roberto Fiorenza, Carmelo Crisafulli, Salvatore Scirè,