کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5147396 | 1497384 | 2016 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Kinetics of hydrogenation of acrylonitrile to propionitrile catalyzed by Raney Ni
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Hydrogenation of acrylonitrile to propionitrile catalyzed by Raney Ni was accessible with good yield and high selectivity under optimized reaction conditions. Kinetic modeling was performed by means of computer aided autoclave reaction; the apparent activation energy of this reaction was determined to be 31.3Â kJ/mol. This reaction is controlled by Raney Ni surface. The reaction is apparently zero-order reaction with respect to acrylonitrile and first-order reaction regarding the concentration of dissolved hydrogen in the liquid phase, respectively.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: International Journal of Hydrogen Energy - Volume 41, Issue 41, 2 November 2016, Pages 18478-18483
Journal: International Journal of Hydrogen Energy - Volume 41, Issue 41, 2 November 2016, Pages 18478-18483
نویسندگان
Xin Ge, Jiongbin Pan, Xinzhi Chen, Chao Qian, Shaodong Zhou,