کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5147419 | 1497384 | 2016 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Mechanistic approach of the electrochemical reduction of CO2 into CO at a gold electrode in molten carbonates by cyclic voltammetry
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The electrochemical transformation of CO2 into more valuable chemicals such as CO offers great interest in the energetic field. In this paper, the feasibility of this valorisation process is investigated by cyclic voltammetry in different binary molten carbonates: Li2CO3Na2CO3 (52:48Â mol. %), Li2CO3K2CO3 (62:38Â mol. %) and Na2CO3K2CO3 (56:44Â mol. %) and in a ternary eutectic: Li2CO3Na2CO3K2CO3 (43.5:31.5:25Â mol. %). The eutectic nature, the oxoacidity, temperature and scanning conditions on the reduction and oxidation peaks is thoroughly analysed. The reduction peak related to CO2 reduction into CO is diffusion-controlled and slow quasi-reversible; in specific experimental conditions, it is split into two peaks of similar intensity. Re-oxidation peaks are most probably due to dissolved and adsorbed CO. Based on our experimental investigation under varied conditions such as molten salt composition, oxoacidity, temperature of the system and thermodynamic predictions regarding carbon presence, two mechanistic schemes are proposed, involving gaseous, dissolved and adsorbed species.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: International Journal of Hydrogen Energy - Volume 41, Issue 41, 2 November 2016, Pages 18706-18712
Journal: International Journal of Hydrogen Energy - Volume 41, Issue 41, 2 November 2016, Pages 18706-18712
نویسندگان
D. Chery, V. Albin, A. Meléndez-Ceballos, V. Lair, M. Cassir,