کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5147732 | 1497360 | 2017 | 12 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Poly(arylene ether)s bounded with disulfonaphthoxyl pendants by post functionalization for polymer electrolyte membrane application in fuel cells
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Poly(arylene ether)s bounded with disulfonaphthoxyl pendants by post functionalization for polymer electrolyte membrane application in fuel cells Poly(arylene ether)s bounded with disulfonaphthoxyl pendants by post functionalization for polymer electrolyte membrane application in fuel cells](/preview/png/5147732.png)
چکیده انگلیسی
A novel series of side-chain type of sulfonated poly(aryl ether) copolymers containing disulfonaphthanoxyl pendants (sSPFAE) were synthesized from 9,9â²-dihydroxyfluorene, 4,4â²-biphenol, decafluorobiphenyl and disodium 4-hydroxy-2,7-naphthalene disulfonate (or dipotassium 7-hydroxy-1,3-naphthalene disulfonate) through two-step aromatic nucleophilic substitution. The structure was characterized by 1H NMR and FTIR. Structure-property relationships of the solution cast sSPFAE membranes, including ion exchange capacity (IECw, weight-based; IECv, volume-based), density, mechanical properties, water swelling, morphology, proton and methanol transport properties, thermal and hydrolytic stability were investigated and compared with those of perfluorinated ionomer (Nafion 112). The inclusion of high content perfluorobiphenyl segments in the sSPFAE back bone and disulfonated naphthalene in the side chain led to moderate water uptake, low swelling, excellent thermal, oxidative and hydrolytic stability. The sSPFAE membranes also exhibited good proton conductivity and low methanol permeability, enabling them good candidates for future polymer electrolyte membrane fuel cell applications.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: International Journal of Hydrogen Energy - Volume 42, Issue 17, 27 April 2017, Pages 12064-12075
Journal: International Journal of Hydrogen Energy - Volume 42, Issue 17, 27 April 2017, Pages 12064-12075
نویسندگان
Zhaoxia Hu, Yao Lu, Xulve Zhang, Qi Gao, Xiaobo Yan, Shouwen Chen,