کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5150730 | 1498681 | 2017 | 17 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Structural diversity of copper(II) amino alcoholate complexes
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کلمات کلیدی
HAPEHAH2-Aminoethanol - 2-آمین اتانول2-Amino-2-hydroxymethyl-1,3-propanediol - 2-آمینو-2-هیدروکسی متیل-1،3-پروپانیدیولAmino alcohols - الکل آمینوX-ray crystallography - بلورنگاری پرتو-ایکسtriethanolamine - تری اتانولامینHAE - جستجوdiethanolamine - دی اتانولینStructural chemistry - شیمی سازهCatalysis - فروکافت یا کاتالیزCopper(II) complexes - مجتمع مس (II)Hexafluoroacetylacetonate - هگزافلوراکتیل اتئوناتHAp - گام
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Amino alcohols which carry both amino and hydroxyl groups in the same molecule are good chelating and bridging ligands. They have been broadly used for the preparation of copper(II) amino alcoholate complexes through the self-assembly process, which generally leads to the formation of diverse structures from mononuclear to polynuclear copper(II) clusters. There are three main factors to control the nuclearity of these clusters: (i) the molar ratio of Cu(II) to amino alcohol, (ii) the choice of the counter anions and (iii) the nature of the amino alcohol. These structures can be used as model systems in magnetic studies, allowing a better understanding about the magnetic interactions between the metal centres, as well as simplified models of the active sites of many copper enzymes, which catalyse the hydroxylation of alkanes and other substrates. This review comprises the literature survey of copper(II) amino alcoholate complexes, presenting the structural diversity from mono- to nonanuclear clusters, from discrete molecules to coordination polymers or networks obtained using small bridging and chelating amino alcoholates with copper(II) ions. Several applications of these complexes have been presented.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Coordination Chemistry Reviews - Volume 347, 15 September 2017, Pages 98-114
Journal: Coordination Chemistry Reviews - Volume 347, 15 September 2017, Pages 98-114
نویسندگان
Petri Seppälä, Reijo Sillanpää, Ari Lehtonen,