کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5151526 | 1499124 | 2017 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Homoleptic mono- and dinuclear complexes of platinum(II) with 1,8-naphthyridine
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Homoleptic mono- and dinuclear complexes of platinum(II) with 1,8-naphthyridine Homoleptic mono- and dinuclear complexes of platinum(II) with 1,8-naphthyridine](/preview/png/5151526.png)
چکیده انگلیسی
Two unprecedented, homoleptic Pt-1,8-naphthyridine complexes have been prepared and characterized. Reaction between 1,8-naphthyridine (napy) and a platinum(II) precursor leads to a mononuclear homoleptic platinum(II) complex with stoichiometry [Pt(napy)4](OTf)2. On the contrary, reaction between napy and a dinuclear platinum(III) precursor produces instead a rare example of a dinuclear, homoleptic, tetracationic platinum(II) complex with stoichiometry [Pt2(napy)4](OTf)4. Crystal structures of both complexes have been obtained. The redox behavior of the dinuclear complex has been studied by cyclic voltammetry, in order to establish its suitability as model precatalyst for organometallic reactions exploiting the Pt(II)/Pt(IV) or Pt(II)/Pt(III) manifold.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganica Chimica Acta - Volume 466, 1 September 2017, Pages 578-583
Journal: Inorganica Chimica Acta - Volume 466, 1 September 2017, Pages 578-583
نویسندگان
Cristina Tubaro, Gilberto Greggio, Sabrina Antonello, Claudia Graiff, Andrea Biffis,