کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5151872 1499137 2016 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
DNA incorporation of a trans-chelating bis-pyridyl ligand for square-planar coordinated metal cations
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
DNA incorporation of a trans-chelating bis-pyridyl ligand for square-planar coordinated metal cations
چکیده انگلیسی
A trans-chelating ligand based on two 2-ethynyl-pyridine arms attached to a benzene ring was incorporated into DNA single strands by means of solid phase phosphoramidite synthesis to provide a tetradentate N4 coordination environment for metal cations favoring a square-planar geometry inside the DNA double helix. The binding of Cu(II) cations was investigated and an increase in the DNA melting temperature was observed upon metal binding.87
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganica Chimica Acta - Volume 452, 1 October 2016, Pages 188-193
نویسندگان
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