An alkaline tin(II) halide compound Na3Sn2F6Cl: Synthesis, structure, and characterization

A zero-dimensional alkaline tin halide compound, Na3Sn2F6Cl, is synthesized by hydrothermal method. Interestingly, both the anions and cations coordinating polyhedra exhibit order arranged with the [SnF3]- trigonal pyramids rotating along the c- axis.218