Syntheses and characterizations of multinuclear, chain and layer silver(I) complexes assembled from bispyridine analogues of pyridinyl-hexahydropyrimidine

Seven complexes have been synthesized by the reaction of AgX (X = NO3− and ClO4−) with three pyridinyl-hexahydropyrimidines which present five types of conformations to connect adjacent Ag(I) cations into diverse fes layers, ladder chains, hexanuclear and dinuclear units.232