کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5156810 | 1500584 | 2017 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Effect of oxidation time on the properties of cellulose nanocrystals from hybrid poplar residues using the ammonium persulfate
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
This work was to investigate the influence of time on the properties of cellulose nanocrystals (CNCs) during the ammonium persulfate (APS) oxidation of hybrid poplar residues (HPHL). The CNCs at the different times were characterized by different techniques. The results showed that CNCs were thinned and shortened with increased oxidation time, and their yield, crystallinity index and zeta potential increased, however, these properties stayed constant after the APS oxidation for 16 h. At this time, the CNC yield was more than 50%, and the CNCs had a zeta potential of â48.84 mV and a CrI of 86.8%. More than 95% of CNCs had a width of 16.87 ± 5.92 nm, and 86.4% of them had a length-to-width ratio from 10 to 30. The primary hydroxyl groups were regioselectively oxidized during the APS treatment. Therefore, the CNCs with stable properties could be extracted from HPHL using APS oxidation.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Carbohydrate Polymers - Volume 174, 15 October 2017, Pages 291-298
Journal: Carbohydrate Polymers - Volume 174, 15 October 2017, Pages 291-298
نویسندگان
Hua Jiang, Yu Wu, Binbin Han, Yang Zhang,