کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5159900 | 1501667 | 2017 | 24 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Dual-ligand complex catalysts for the cycloaddition of propylene oxide and carbon dioxide
ترجمه فارسی عنوان
کاتالیزورهای پیچیده دوگانه لیگند برای سیکل پاشش اکسید پروپیلن و دی اکسید کربن
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
چکیده انگلیسی
This paper reported some dual-ligand complexes composed of ZnBr2, N-methylimidazole(NMI) and ammonium bromine. The entire complexes were characterized by different spectroscopic techniques. The X-ray crystallography data of sample ZnBr2/tetra methyl ammonium bromide/N-methylimidazole displayed that the Zn atom was coordinated with three bromine atoms, a nitrogen atom, and an independent cation to form the tetracoordinated complex. However, the other samples cannot form the structure, which plays an important role in the catalytic performances due to the limitation of some characteristics of the ammonium bromine. The catalytic activity of the formed complex containing active leaving group was higher than that of non-containing active leaving group. And the catalytic activity for the cycloaddition of propylene oxide and carbon dioxide enhanced dramatically, in which the yield of propylene carbonate could be more than 85% at the mild conditions.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Structure - Volume 1150, 15 December 2017, Pages 329-334
Journal: Journal of Molecular Structure - Volume 1150, 15 December 2017, Pages 329-334
نویسندگان
Qi-Yue Yuan, Peng Zhang, Yan-Li Shi, Ding-Hua Liu,