Molecular characterization, DFT and TD-DFT calculations of morpholinium tetra chloropalladate (II)

The asymmetric unit of the salt is formed by discrete groups consisting of the PdCl42− anion and one N(mor) protonated C4H10ON+cations without appreciable Pd⋯N interactions. The PdCl42− and C4H10ON+was connected through the 2 dimensional H-bonding between them. The Figure portrayed the hydrogen bonding network along b-axis of the compound. This shows that the tetrahedral palladium form the twisted chair like hydrogen bonding between the four neighborhoods of the C4H10ON+ ion.151