کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5162249 | 1502285 | 2014 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Flash pyrolysis of kerogens from algal rich oil shales from the Eocene Huadian Formation, NE China
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The hydrocarbon composition of the kerogen fractions of two samples (HD-20 and HD-21) from oil shale layer 4 in the Eocene Huadian Formation, NE China were investigated by analytical flash pyrolysis (650 °C/10 s) followed by gas chromatography-mass spectrometry (Py-GC-MS). Organic petrography showed that the two kerogens were almost entirely derived from algal remains but contained very different algal maceral compositions, with 40% of the macerals in HD-20 being of macroalgal origin that were not present in HD-21. Py-GC-MS yielded high concentrations of n-alkanes from both kerogens, but with different molecular weight profiles due to the different algal contributors to the two kerogen samples. The hydrocarbon pyrolysates generated at 650 °C from HD-21 in which the green microalga Botryococcus braunii was identified showed a higher proportion of longer chain alkanes and alkenes presumably from cracking of the botryococcus algaenan. We also identified a C40 monoaromatic lycopane derivative, which was absent in the HD-20. The high hydrocarbon potential of both kerogens can be attributed to common microalgal sources, whereas the macroalgae, which is abundant in HD-20, makes only a minor contribution to the hydrocarbon products.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Organic Geochemistry - Volume 76, November 2014, Pages 167-172
Journal: Organic Geochemistry - Volume 76, November 2014, Pages 167-172
نویسندگان
Zhirong Zhang, John K. Volkman, Paul F. Greenwood, Wenxuan Hu, Jianzhong Qin, Tenger Borjigin, Changbo Zhai, Weixin Liu,