کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5162317 | 1502287 | 2014 | 28 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Experimental investigations about the effect of pressure on gas generation from coal
ترجمه فارسی عنوان
تحقیقات تجربی در مورد اثر فشار بر تولید گاز از زغال سنگ
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
چکیده انگلیسی
Closed-system pyrolysis experiments were conducted on a coal sample with a maturity of 0.57Â %Ro using gold tubes pressured to 10Â MPa, 25Â MPa, 50Â MPa, 75Â MPa and 100Â MPa to investigate the influence of increasing pressure on gas generation. The variation of gaseous components generated by coal, the H/C atomic ratio and the vitrinite reflectance of pyrolysis residues with pressure and temperature indicate that pressure does not linearly impact gas generation from coal. Pressure has no effect on primary gas generation, but it does affect secondary gas generation. Retardation of secondary generation is highest at 50Â MPa. Our investigations reveal that previously published and partly opposing results about the effect of pressure on hydrocarbon generation can be mainly explained by the difference in the pressure range under which those experiments were conducted. Our experimental results demonstrate that hydrocarbon generation is generally least retarded at pressures exceeding 75Â MPa. Nevertheless, hydrocarbon generation in natural systems usually occurs at pressures of 10-60Â MPa (1-6Â km burial depth) and might therefore be secondarily controlled by pressure retardation effects.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Organic Geochemistry - Volume 74, September 2014, Pages 116-122
Journal: Organic Geochemistry - Volume 74, September 2014, Pages 116-122
نویسندگان
Jingkui Mi, Shuichang Zhang, Kun He,