Jurassic oils in the central Sichuan basin, southwest China: Unusual biomarker distribution and possible origin

Crude oils in the Jurassic reservoirs of the Shilongchang oilfield in central Sichuan basin are characterized by a high abundance of methylcyclohexane relative to n-heptane in the C7 light hydrocarbons, high pristane/phytane ratio (Pr/Ph 1.81-2.45), a C29 sterane dominance and a tendency towards lower δ 13C values with increasing chain length for C12-C19n-alkanes, reflecting a dominantly terrigenous source deposited in a sub-oxic to oxic environment. The oils are extremely enriched in rearranged hopanes, including 17α(H)-diahopanes, 18α(H)-neohopanes and an unidentified rearranged hopane series with relatively short gas chromatography (GC) retention times. The 17α(H)-diahopanes are present in highest abundance among the hopane classes and exhibit similar carbon number distributions to those of the 17α(H)-hopanes, including a range from C27 to C35, a dominance of the C30 isomer and presence of 22S and 22R epimers for C31-C35 homologues. The 18α(H)-neohopanes are less abundant than the 17α(H)-diahopanes, with only Ts, C29Ts and a possible C30 member detected. The early eluting rearranged hopanes extend from C29 to C35 and display distributions similar to the 17α(H)-hopanes and 17α(H)-diahopanes. As the origin of rearranged hopanes is relatively well understood, their unusually high relative abundance in the studied Jurassic lacustrine oils from the central Sichuan basin provides strong evidence for the presence of effective highly mature and clay-rich source rocks formed under a sub-oxic depositional setting.