The bioconversion of 5-deoxystrigol to sorgomol by the sorghum, Sorghum bicolor (L.) Moench

► The bioconversion of 5-deoxystrigol (5-DS) in sorghum (Sorghum bicolor) to sorgomol was established. ► The LC-MS/MS analyses established conversion of 5-DS and ent-2′-epi-5-DS to sorgomol and ent-2′-epi-sorgomol, respectively. ► The conversion is most likely catalyzed by a cytochrome P450.