کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5165283 | 1502401 | 2012 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
In vitro analysis of the monolignol coupling mechanism using dehydrogenative polymerization in the presence of peroxidases and controlled feeding ratios of coniferyl and sinapyl alcohol
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
⺠Oxidizability of coniferyl alcohol (CA) and sinapyl alcohol (SA) for the peroxidases were estimated in the order of Coprinus cinereus peroxidase (CiP) > soybean peroxidase (SBP) > horseradish peroidase (HRP), SBP > CiP > HRP, respectively. ⺠The dehydrogenative polymerisates (DHP) yields were DHP-C (9-72%) â DHP-H (7-69%) > DHP-S (0-27%). ⺠The average molecular weights of the DHPs were between 3,400 and 5,000 Da, which was only ca. 1/2-1/3 that of native MWL. ⺠The frequency of the β-O-4 linkage formation, especially with CA, was influenced by type of peroxidases used.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Phytochemistry - Volume 82, October 2012, Pages 15-21
Journal: Phytochemistry - Volume 82, October 2012, Pages 15-21
نویسندگان
Sun-Joo Moon, Mi Kwon, Donha Choi, Keehoon Won, Yong Hwan Kim, In-Gyu Choi, Joon Weon Choi,