کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5173580 1380641 2013 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Macrantaline and macrantoridine, new alkaloids from a turkish sample of Papaver pseudo-orientale
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
Macrantaline and macrantoridine, new alkaloids from a turkish sample of Papaver pseudo-orientale
چکیده انگلیسی
The major alkaloids of the aerial parts of a Turkish sample of Papaver pseudo-orientale are salutaridine and a new alkaloid, macrantaline, UV, IR, PMR, MS and CD have been used to establish the structure of macrantaline as 1-(2′-hydroxymethylene-3′,4′-dimethoxybenzyl)-2-methyl-6,7-methylenedioxy-8-methoxy-1,2,3,4-tetrahydroisoquinoline. The corresponding 2′-methyl substituted analogue prepared from (−)-α-narcotine and also from macrantaline proved to have identical properties, including CD spectra, thus confirming the structure and establishing the absolute configuration of macrantaline. A new minor alkaloid, macrantoridine, yielded macrantaline on lithium aluminium hydride reduction and differs from the latter in that the 2′-substituent is a carboxyl instead of hydroxymethylene. UV, IR, PMR, MS and CD data are reported for macrantoridine.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Phytochemistry - Volume 16, Issue 12, 1977, Pages 2009-2013
نویسندگان
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