کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5178481 | 1502498 | 2017 | 12 صفحه PDF | دانلود رایگان |
- A facile strategy to anchor MWCNTs at the interface of PLLA/EGD blends has been reported.
- Many MWCNTs are firmly anchored at the blend interface by SC crystallites.
- The SC crystallites can be rapidly formed at the blend interface during melt mixing.
- The anchored MWCNTs can remarkably enhance interfacial strength and impact toughness of the blends.
- The interfacial localization of MWCNTs facilitates the formation of conductive pathway.
Selective localization of nanoparticles at the interface of immiscible polymer blends has been witnessed as an efficient method to improve blend properties and even provide some added functionalities. Nevertheless, it is still a great challenge to achieve thermodynamically stable interface-localization of the nanoparticles mainly due to their low interfacial stabilities as well as high transfer speeds between the blend phases, especially for those with high aspect ratios. In this work, taking poly(l-lactide)/poly(d-lactide) grafted ethylene-acrylic ester copolymer/multi-walled carbon nanotubes (PLLA/EGD/MWCNTs) ternary composite as an example, we describe a new and facile strategy to address this challenge via anchoring high-aspect-ratio MWCNTs at the interface of PLLA/EGD blends using interface-localized stereocomplex (SC) crystallites as anchoring agents. During melt mixing of EGD with PLLA/MWCNTs mixture, such SC crystallites can be rapidly formed at the blend interface to prevent MWCNTs transferring from the thermodynamically unfavorable PLLA matrix into favorable EGD phase as physical barriers, and meanwhile some of these transferring MWCNTs could serve as nucleating agents to induce SC crystallization on their surfaces. As a result, many MWCNTs are firmly anchored at the blend interface by these SC crystallites. The anchored MWCNTs can not only function as effective interfacial enhancers to remarkably enhance interfacial strength and resulting impact toughness of PLLA/EGD blends but also enable the formation of electrical conductive pathway in the network-like PLLA/EGD blends at a much lower percolation threshold. This wok could offer a promising opportunity for preparing high-performance and multifunctional PLLA-based composites through controlling particle localization at the interface of immiscible PLLA blends with the aid of SC crystallization.
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Journal: Polymer - Volume 108, 13 January 2017, Pages 38-49