کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5179712 | 1502525 | 2015 | 6 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Transparent and high permittivity films of poly(methyl methacrylate)-grafted 7Â nm barium titanate particles prepared by surface-initiated atom transfer radical polymerization Transparent and high permittivity films of poly(methyl methacrylate)-grafted 7Â nm barium titanate particles prepared by surface-initiated atom transfer radical polymerization](/preview/png/5179712.png)
- PMMA-grafted 7Â nm BaTiO3 (BT) particles form transparent and high-dielectric films.
- The film with a 10 vol% BT fraction has a dielectric constant of 4.1.
- 100Â mm thickness films have 80% visible light transmittance.
Transparent and high permittivity films were prepared by melt pressing poly(methyl methacrylate) (PMMA)-grafted 7 nm barium titanate (BT) particles. PMMA chains with molecular weights of 32-40 kDa were grafted on BT particle surfaces at a density of 0.2-0.7 chains nmâ1 through surface-initiated atom transfer radical polymerization of methyl methacrylate. This yielded BT/PMMA composites with BT volume fractions (Ï) ranging from 3.2% to 10%. In melt-pressed BT/PMMA composite films, BT particles were well-dispersed and exhibited high transmittance at 550 nm, with the values standardized for 100 μm thickness being 80%. The relative permittivity of the films at 1 kHz and 25 °C increased to 4.1 upon increasing Ï to 10%, according to Lichtenecker's logarithmic mixture formula, while the loss tangent remained as low as 0.04.
Journal: Polymer - Volume 81, 16 December 2015, Pages 23-28