کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5180459 | 1502544 | 2015 | 9 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Synthesis and properties of poly(aryl ether sulfone)s incorporating cage and linear organosiloxane in the backbones Synthesis and properties of poly(aryl ether sulfone)s incorporating cage and linear organosiloxane in the backbones](/preview/png/5180459.png)
A series of novel copoly(aryl ether sulfone)s with polydimethyl (PDMS) and double-decker-shaped silsesquioxane (DDSQ) in the main chain were synthesized by nucleophilic substitution polymerization approach. Dihydroxy terminated eugenosiloxanes (2OH-PDMS-n) and 3,13-di(2-methoxy-4-propylphenol)octaphenyl DDSQ (2OH-DDSQ) were synthesized. These two difunctional oligomers were used to copolymerize with 4-fluorophenyl sulfone to obtain poly(aryl ether sulfone) containing cage and linear organosiloxane (Si-PES) through one-step high-temperature solution method. Si-PES with multiple PDMS and DDSQ contents in the main chains were obtained by adjusting the molecular weight of 2OH-PDMS-n and controlling the molar ratio of 2OH-DDSQ to 2OH-PDMS-n. The dielectric constants sharply decreased as organosiloxane was introduced compared with traditional PES which the lowest value was achieved at 5% DDSQSi-PES (2.36 at 1 MHz). In addition, enhanced hydrophobic capacity peaks were obtained at 50% DDSQSi-PES surface hydrophobicity (113°) as the synergies of both linear organosiloxane and DDSQ. Furthermore, thermal and crystallization behaviors, as well as surface properties, were investigated.
Journal: Polymer - Volume 62, 7 April 2015, Pages 77-85