کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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5181457 | 1380963 | 2014 | 6 صفحه PDF | دانلود رایگان |
We performed dynamic Monte Carlo simulations of isothermal crystallization of bulk polymers at a high temperature, which was induced by a homogeneous stretching with a constant strain rate over a wide range of strains. We observed that the crystallites exhibit variable trends of chain folding in three sequential regions of strains, revealing hierarchical mechanisms of strain-induced polymer crystallization: in the first region, sporadic stretched segments initiate intermolecular crystal nucleation with less chain folding at higher strains; in the second region, massive less-stretched segments perform crystal growth with more chain folding at higher strains; in the third region, those folded chains extend via a melting-recrystallization process, again with less chain folding at higher strains. Different trends of chain-folding between crystal nucleation and growth appear intrinsic and ultimately lead to shish-kebab crystals. Our observations provided a molecular-level rationale to understand various experimental phenomena upon the processing for oriented semi-crystalline polymers.
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Journal: Polymer - Volume 55, Issue 5, 10 March 2014, Pages 1267-1272