کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5182716 1380997 2013 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Imidazolium-functionalized poly(arylene ether sulfone) block copolymer as an anion exchange membrane for alkaline fuel cell
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
Imidazolium-functionalized poly(arylene ether sulfone) block copolymer as an anion exchange membrane for alkaline fuel cell
چکیده انگلیسی

An ethyl imidazolium-functionalized poly(arylene ether sulfone) (EI-PES) block copolymer was prepared as a novel anion exchange membrane. The EI-PES polymer was synthesized by polycondensation between the F- and OH-terminated oligomers, followed by benzylic bromination and imidazolium functionalization (homogeneous functionalization). The quaternary ammonium-functionalized PES (QA-PES) was also prepared by heterogeneous functionalization, and the properties were compared with EI-PES. The membrane obtained from EI-PES showed a well-defined phase separated morphology between hydrophobic and hydrophilic ionic units of the block copolymer. An IEC of 1.45 meq/g with hydroxide conductivity of 0.03 S/cm at r.t. was observed for EI-PES. The EI-PES membrane also displayed excellent dimensional, thermal, mechanical and chemical stabilities.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polymer - Volume 54, Issue 1, 8 January 2013, Pages 111-119
نویسندگان
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