کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5182996 | 1381005 | 2012 | 11 صفحه PDF | دانلود رایگان |
The interdiffusion of two materials used to fabricate polymeric gradient refractive index (GRIN) lenses was examined by varying contact time during multilayer films co-extrusion composed of alternating poly(methylmethacrylate) (PMMA) and poly(styrene-co-acrylonitrile) with 17 mol% acrylonitrile (SAN17). The model applied successfully described their interdiffusion, and a reasonable mutual diffusion coefficient of 7.0 Ã 10â13 m2/s was determined. Atomic force microscopy confirmed good agreement between modeled profiles and actual layer structure, and optical properties were investigated. Films with contact times of â¤160 s exhibited multiple refractive indices, while films with longer contact times, showed single refractive indices that followed an additive line. Though a single additive value requires layers ⤠a quarter-wavelength of light, these films exhibit such behavior with thicknesses 5à greater than expected, though layer resolution is still present. Using the model profiles, it was determined that only a 1% reduction in material purity is required to reduce the effective layer thickness.
Journal: Polymer - Volume 53, Issue 6, 9 March 2012, Pages 1393-1403