کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5183429 1381018 2012 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Statically non-wetting electrospun perfluorocyclobutyl (PFCB) aryl ether polymer doped with room temperature ionic liquid (RTIL)
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
Statically non-wetting electrospun perfluorocyclobutyl (PFCB) aryl ether polymer doped with room temperature ionic liquid (RTIL)
چکیده انگلیسی

A statically non-wetting, electrospun surface of non volatile room temperature ionic liquid (RTIL), 1-butyl-3-methylimidazolium hexafluorophosphate, (BMIM-PF6), hosted in a solution-processable, semi-fluorinated perfluorocyclobutyl (BP-PFCB) aryl ether polymer was successfully prepared by electrospinning and compared with a surface prepared by spin casting. The surface properties of undoped and BMIM-PF6 doped systems were analyzed by water contact angle (WCA) and atomic force microscopy (AFM). BMIM-PF6 doped BP-PFCB surfaces prepared by spin casting showed a WCA of 90° while non-woven electrospun surfaces with the same BMIM-PF6 concentration showed high degree of hydrophobicity with a WCA greater than 150°. Morphologies of the electrospun surfaces were characterized by scanning electron microscopy (SEM). The surface composition was analyzed by energy-dispersive X-ray spectroscopy (EDXS) and attenuated total reflectance infrared spectroscopy (ATR-IR). Thermal analysis of the electrospun, non-woven surfaces of the doped and the undoped system of BP-PFCB were done by TGA.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polymer - Volume 53, Issue 11, 9 May 2012, Pages 2211-2216
نویسندگان
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