کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5185028 | 1381064 | 2011 | 9 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Epoxy/graphene platelets nanocomposites with two levels of interface strength Epoxy/graphene platelets nanocomposites with two levels of interface strength](/preview/png/5185028.png)
Graphene platelets (GP) are a novel class of nanofillers due to its good compatibility with most polymers, high aspect ratio, high absolute strength and cost-effectiveness. We in this study synthesised two types of epoxy/GP nanocomposites with different interface strength using the combination of sonication and chemical modification. Although the surface-modified graphene platelets (m-GP) formed clusters, a higher degree of dispersion and exfoliation of graphene was observed in each cluster owning to the improved interface by modification. The scrolling of graphene was found predominantly in the interface-modified nanocomposite. At 4 wt%, the modified nanocomposite shows fracture energy release rate G1c 613.4 J mâ2, while the unmodified nanocomposite indicates 417.3 J mâ2, in comparison with neat epoxy G1c 204.2 J mâ2. The interface modification enhanced the glass transition temperature of neat epoxy from 94.7 to 108.6 °C, 14.7% increment. Toughening mechanisms are attributed to the voiding, microcracking and breakage of GP, while matrix may not consume as much fracture energy as m-GP do.
Journal: Polymer - Volume 52, Issue 7, 23 March 2011, Pages 1603-1611