کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5185054 1381065 2009 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Electrochemically and electrochromically stable polyimides bearing tert-butyl-blocked N,N,N′,N′-tetraphenyl-1,4-phenylenediamine units
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
Electrochemically and electrochromically stable polyimides bearing tert-butyl-blocked N,N,N′,N′-tetraphenyl-1,4-phenylenediamine units
چکیده انگلیسی

A new class of electrochemically active polyimides with di-tert-butyl-substituted N,N,N′,N′-tetraphenyl-1,4-phenylenediamine units was prepared from N,N-bis(4-aminophenyl)-N′,N′-bis(4-tert-butylphenyl)-1,4-phenylenediamine and various aromatic tetracarboxylic dianhydrides via a conventional two-step procedure that included a ring-opening polyaddition to give poly(amic acid)s, followed by chemical or thermal cyclodehydration. Most of the polyimides are readily soluble in many organic solvents and can be solution-cast into tough and amorphous films. They had useful levels of thermal stability, with relatively high glass-transition temperatures (276-334 °C), 10% weight-loss temperatures in excess of 500 °C, and char yields at 800 °C in nitrogen higher than 60%. Cyclic voltammograms of the polyimide films cast on the indium-tin oxide (ITO)-coated glass substrate exhibited two reversible oxidation redox couples at 0.70-0.74 V and 1.05-1.08 V vs. Ag/AgCl in acetonitrile solution. The polyimide films revealed excellent stability of electrochromic characteristics, with a color change from colorless or pale yellowish neutral form to green and blue oxidized forms at applied potentials ranging from 0.0 to 1.3 V. These anodically coloring polymeric materials exhibited high optical contrast of percentage transmittance change (Δ%T) up to 44% at 413 nm and 43% at 890 nm for the green coloration, and 98% at 681 nm for the blue coloration. After over 50 cyclic switches, the polymer films still exhibited good redox and electrochromic stability.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polymer - Volume 50, Issue 7, 20 March 2009, Pages 1692-1699
نویسندگان
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