کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5185558 1381081 2010 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Synthesis and characterization of triptycene type cross-linker and its use in photoinduced curing applications
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
Synthesis and characterization of triptycene type cross-linker and its use in photoinduced curing applications
چکیده انگلیسی

A novel triptycene type diacrylate cross-linker, triptycene hydroquinone diacrylate (THDA) was synthesized from the reaction of triptycene hydroquinone with acryloyl chloride and characterized. The photocuring behaviour and the reaction kinetics of the synthesized cross-linker were investigated by means of photo-differential scanning calorimetry (photo-DSC) experiments. Formulations containing monofunctional (meth)acrylate monomers, namely glycidyl methacrylate (GMA), 2-hydroxyethyl acrylate (HEA), 2-hydroxyethyl methacrylate (HEMA), and 2-ethylhexyl methacrylate (EHMA), cross-linker, THDA and 2,2-dimethoxy-2-phenylacetophenone (DMPA) as a photoinitiator were irradiated. A conventional cross-linker without triptycene unit such as hydroquinone diacrylate (HDA) was used under the same conditions for comparison. The effects of the structure of the monofunctional monomer and triptycene moiety on the photopolymerization kinetics were evaluated and discussed.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polymer - Volume 51, Issue 4, 15 February 2010, Pages 825-831
نویسندگان
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